1,1′-(9-Octyl-9H-carbazole-3,6-diyl)diethanone

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2,7-Dibromo-9-octyl-9H-carbazole

In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π-π inter-actions; the smallest centroid-to-centroid distance is 4.2822 (11) Å. This offset packing motif allows the methyl-ene group attached directly to the N atom...

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1,1′-(9-Octyl-9H-carbazole-3,6-di­yl)diethanone

The central structural element of the title compound, C(24)H(29)NO(2), is a carbazole unit substituted with two acetyl residues and an octyl chain. The acetyl residues are nearly coplanar [dihedral angles = 5.37 (14) and 1.0 (3)°] with the carbazole unit which is essentially planar (r.m.s. deviation for all non-H atoms = 0.025 Å). The octyl chain adopts an all-trans conformation. The crystal pa...

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2,7-Bis(2-nitro­phen­yl)-9-octyl-9H-carbazole

The title compound, C(32)H(31)N(3)O(4), was obtained in a Suzuki coupling of carbazole diboronic acid and bromo-nitro-benzene. In the crystal, the mol-ecule adopts a non-symmetric conformation. The carbazole ring system is approximately planar [maximum deviation from the least-squares plane = 0.039 (2) Å]. The planes of the carbazole unit and the benzene rings subtend dihedral angles of 48.42 (...

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9-Ethynyl-9H-carbazole

The title compound, C(14)H(9)N, is the second crystallographically characterized example of an ynamine with an H atom in the C-terminal position. There are two independent mol-ecules (A and B) in the asymmetric unit. The structures of both mol-ecules are essentially planar (r.m.s. deviation = 0.0312 and 0.0152 Å). The N-C(sp) bond lengths are 1.353 (4) and 1.350 (4) Å, and those of the acetyl-e...

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9-Benzyl-9H-carbazole

The asymmetric unit of the title compound, C(19)H(15)N, contains two crystallographically independent mol-ecules. In both mol-ecules, the planar carbazole moieties [maximum deviations = 0.037 (4) and 0.042 (3) Å] are oriented with respect to the adjacent benzene rings, at dihedral angles of 85.29 (8) and 89.89 (7)°, respectively. In the crystal structure, weak C-H⋯π inter-actions are observed i...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810028928